Group 6 Cations

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Cations

Group 6 consists of copper 2+ blue cation, mercury 2+ colourless cation,

Cations Group 6 consists of copper 2+ blue cation, mercury 2+ colourless
cobalt 2+ pink cation and nickel 2+ green cation.

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Common reagent

The common reagent of this group is aqueous ammonia solution NH4OH.

Common reagent The common reagent of this group is aqueous ammonia solution
When ammonia solution is added, cations of this group form precipitates of various colors. 

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When excess ammonia solution is added, these precipitates will dissolve into colorful

When excess ammonia solution is added, these precipitates will dissolve into colorful solutions.
solutions.

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Determination

Copper 2+
We can use a flame test and see the blue-green flame.
Also

Determination Copper 2+ We can use a flame test and see the
we can use the reaction with potassium ferrocyanide K4[Fe(CN)6]. This reaction yields to the formation of brown-red precipitate Cu2[Fe(CN)6].

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Mercury 2+
We can use the reaction with potassium iodide KI. The brown-red

Mercury 2+ We can use the reaction with potassium iodide KI. The
precipitate of mercury iodide HgI2 is formed.

Hg2+ + KI = HgI2↓ + K+

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Cobalt 2+
We can use the reaction ammonium thiocyanate NH4SCN. The solution turns

Cobalt 2+ We can use the reaction ammonium thiocyanate NH4SCN. The solution
to blue. For this reaction we should use an organic compound for extraction.

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Nickel 2+
We can use the reaction with Dimethylglyoxime. The crimson precipitate is

Nickel 2+ We can use the reaction with Dimethylglyoxime. The crimson precipitate is formed.
formed.

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Application

Compounds of Group 6 cations found a use in medicine and pharmacy.

Application Compounds of Group 6 cations found a use in medicine and
For example, mercury oxide is a part of some medicinal creams, mercury chloride and copper sulfate are used in antiseptics.
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